COMPLEX COMPOUNDS WITH PHOSPHORUS AND NITROGEN CONTAINING LIGANDS

IsN NMR Spectroscopy of Phosphorus-Nitrogen Compounds

A systematic study of sensitil'ilY enhancement in ' ~N NMR spectra of phosphorus-nilrogf'o compounds by 3IP.I5N polariSlllion tfllrtsff'r \'l as .,..rformed !ISing Iris-(dimethylamioo)phosphine ( I) as a model compound. The application of sen!ral mul1ipulse lechoiques (refocussed and oon-rdocussed INEPT. DEPT) lind dccoupling sclw>mes shows lh:tl muimum enhaocement \'I'as reached \'lith fhe non...

Dirhodium formamidinate compounds with bidentate nitrogen chelating ligands.

The reactions of [Rh(2)(DTolF)(2)(CH(3)CN)(6)][BF(4)](2) (1) (DTolF = N,N'-di-p-tolylformamidinate) with 2,2'-bipyridine (bpy) and 1,10-phenanthroline (phen) proceed with substitution of CH(3)CN molecules to give products with the N-N ligands chelating in an equatorial-equatorial (eq-eq) fashion. Compound 1 reacts with 1 equiv of bpy to yield a mixture of [Rh(2)(DTolF)(2)(bpy)(CH(3)CN)(3)][BF(4...

ORGANIC CHEMISTRY Organic Compounds containing Nitrogen

Chemistry of dihydrogen complexes containing only phosphorus co-ligands

A series of new dicationic dihydrogen complexes of ruthenium of the type cis-[(dppm)2Ru(η-H2)(L)][BF4]2 (dppm = Ph2PCH2PPh2; L = phosphite) have been prepared by protonating the precursor hydride complexes cis[(dppm)2Ru(H)(L)][BF4] using HBF4•Et2O. The precursor hydride complexes have been obtained from trans-[(dppm)2Ru(H)(L)][BF4] (L = phosphite) via a rare acidcatalysed isomerization reaction...

Luminescent platinum complexes containing phosphorus-linked silole ligands.

A series of Pt(ii) complexes containing silole-based ligands with diphenylphosphino groups terminally bound to a conjugated organic linker unit coordinated to the silole ring in the 2- or 2,5-positions, 1,1-dimethyl-2-(5'-diphenylphosphino-2'-thienyl)-3,4-diphenylsilole (4), 1,1-dimethyl-2,5-bis(5'-diphenylphosphino-2'-thienyl)-3,4-diphenylsilole (5), and 1,1-dimethyl-2,5-bis(4'-diphenylphosphi...